AHCI Controllers can be Switchable or AHCI only. There is a flag in the HBA Memory Registers that reflects this. If it is switchable, then you can set bits that put the Controller into AHCI Mode or IDE Mode.
Otherwise the Controller does not support IDE Mode, or in at least one case not properly. No software can override this.
If the Controller is switchable, but the associated BIOS is not, you may be able to reflash with a new BIOS if one can be found, made or hacked.
Alternatively, Drives can be accessed by switching the Mode to IDE with Software.