Of course it is not possible to launch anything above Chrome 102 as of version 3.0.1 (and 75 for XP 64), however it is possible to launch above 102 (including Supermium/CatsXP 117/118) on XP 32 by adding some DLLs from Wine 8.16 staging (ncrypt and bcrypt) next to chrome.exe and add "--no-sandbox --single-process --disable-webgl". Just tested it on a VM and it seems to work fine (You still can't download files/extensions).
Edit: Since One Core API version 3.0.2 got released, you don't need those DLLs from Wine, just set compatibility mode to Vista and it should work (add --no-sandbox if it doesn't start). You most likely don't need to install One Core API when win32ss successfully ported Supermium to XP.